[1]唐志敏,张晓东,张明,等.新安江流域土壤元素地球化学特征:来自岩石建造类型的约束[J].华东地质,2023,44(02):172-185.[doi:10.16788/j.hddz.32-1865/P.2023.02.006]
　TANG Zhimin,ZHANG Xiaodong,ZHANG Ming,et al.Geochemical characteristics of soil elements in Xin’an River Basin: constraints from rock formation types[J].East China Geology,2023,44(02):172-185.[doi:10.16788/j.hddz.32-1865/P.2023.02.006]
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新安江流域土壤元素地球化学特征:来自岩石建造类型的约束()
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《华东地质》[ISSN:2096-1871/CN:32-1865/P]

卷:
44
期数:
2023年02期
页码:
172-185
栏目:
土壤资源专题
出版日期:
2023-06-17

文章信息/Info

Title:
Geochemical characteristics of soil elements in Xin’an River Basin: constraints from rock formation types
作者:
唐志敏1;  张晓东1;  张明1;  周墨1;  田福金1;  王尚晓1;  马青山1;  王冲1;  张洁1;  牛晓楠1;  宗乐丽1;  黄丁伶2
1. 中国地质调查局南京地质调查中心, 江苏 南京 210016;
2. 中国人民解放军陆军工程大学, 江苏 南京 210007
Author(s):
TANG Zhimin1;  ZHANG Xiaodong1;  ZHANG Ming1;  ZHOU Mo1;  TIAN Fujin1;  WANG Shangxiao1;  MA Qingshan1;  WANG Chong1;  ZHANG Jie1;  NIU Xiaonan1;  ZONG Leli1;  HUANG Dingling2
1. Nanjing Center, China Geological Survey, Nanjing 210016, Jiangsu, China;
2. Army Engineering University of PLA, Nanjing 210007, Jiangsu, China
关键词:
土壤; 岩石建造; 元素; 地球化学; 新安江流域
Keywords:
soil; rock formation; elements; geochemistry; Xin’an River Basin
分类号:
P595P642.13
DOI:
10.16788/j.hddz.32-1865/P.2023.02.006
摘要:
成土母岩是土壤形成发育的物质基础,其岩石建造类型为土壤的元素地球化学特征提供重要约束。针对新安江流域各类岩石建造发育的土壤,以小流域为调查单元开展了生态地球化学调查,系统开展了不同地质背景下不同层位的土壤及相应母岩的对比研究,获取了该流域主要岩石建造土壤层、成土母质层以及成土母岩等介质中的主量元素、养分元素、重金属元素及其他有益元素的分布及分配特征。结果表明:各类元素在同一土壤-成土母质-成土母岩体系中的地球化学特征表现出一致性,除部分主量元素及pH值在不同岩石建造发育的土壤中存在较小差异外,大部分元素在新安江流域土壤中的组成及分布显著受其成土母岩的岩石建造类型控制。其中,黑色岩系及碳酸盐岩发育的土壤与全区背景差异最大,显著富集Cd、Cu、Se、Mo等亲硫元素,存在一定的环境质量风险;红层发育的土壤普遍缺乏N、P、有机质等养分元素,火山岩与侵入岩发育的土壤普遍富K元素,碎屑岩与变质岩发育的土壤元素地球化学特征与全流域背景差异较小。
Abstract:
The pedogenic rock is the material basis for the soil formation and development, and its rock formation type provides important constraints for the element geochemical characteristics of the soil. For the soils originated from various types of rock formation in Xin’an River Basin, the ecological geochemical survey was carried out in the small watershed as the investigation unit. A comparative study of soils and corresponding parent rocks at different horizons under different geological settings was systematically conducted, obtaining the distribution and partitioning characteristics of major elements, nutrient elements, heavy metal elements and other beneficial elements in soil layer, parent material layer and pedogenic rock of the main rock formation in Xin’an River Basin. The results indicate consistent geochemical characteristics of various elements in the soil, parent material and pedogenic rock. The composition and distribution of most elements in the soil of Xin’an River Basin are apparently controlled by the rock formation type of their pedogenic rock, except some major elements and pH values showing minor difference among the soils sourced from different rock formations. The soil developed from black rock series and carbonate rock is the most different from the background of the whole region, which is significantly enriched with sulphophile elements such as Cd, Cu, Se, Mo, existing a certain environmental quality risk. The soil derived from red beds is generally lack of N, P and organic matter, while that from volcanic rocks and granite is generally rich in K. The geochemical characteristics of the soil elements come from clastic rocks and metamorphic rocks are slightly different from the background of the whole basin.

参考文献/References:

[1] 王学求,柳青青,刘汉粮,等.关键元素与生命健康:中国耕地缺硒吗?[J].地学前缘,2021,28(3):412-423. WANG X Q, LIU Q Q, LIU H L, et al. Key elements and human health: Is China’s arable land selenium-deficient?[J]. Earth Science Frontiers,2021,28(3): 412-423.
[2] 汪立今,刘智艳.环境地球化学与人体健康关系的探讨[J].地质地球化学,2000,28(3):93-96. WANG L J, LIU Z Y. Probe into the relation between environmental geochemistry and human health[J]. Geology-Geochemistry, 2018, 28(3):93-96.
[3] 武春林,王瑞廷,丁坤,等.中国土壤质量地球化学调查与评价的研究现状和进展[J].西北地质,2018,51(3):240-252. WU C L, WANG R T, DING K, et al. Geochemical survey and evaluation on soil quality in China: Research status and advances[J]. Northwestern Geology, 2018, 51(3): 240-252.
[4] 李括,彭敏,赵传冬,等.全国土地质量地球化学调查二十年[J].地学前缘,2019,26(6):128-158. LI K, PENG M, ZHAO C D, et al. Vicennial implementation of geochemical survey of land quality in China[J]. Earth Science Frontiers, 2019, 26(6):128-158.
[5] 成杭新,彭敏,赵传冬,等.表生地球化学动力学与中国西南土壤中化学元素分布模式的驱动机制[J].地学前缘,2019,26(6):159-191. CHENG H X, PENG M, ZHAO C D, et al. Epigenetic geochemical dynamics and driving mechanisms of distribution patterns of chemical elements in soil, Southwest China[J]. Earth Science Frontiers, 2019, 26(6): 159-191.
[6] 严明书,黄剑,何忠庠,等.地质背景对土壤微量元素的影响——以渝北地区为例[J].物探与化探,2018,42(1):199-205. YAN M S, HUANG J, HE Z Y, et al. The influence of geological background on trace elements of soil: A case study of Yubei area[J]. Geophysical and Geochemical Exploration, 2018, 42(1): 199-205.
[7] KASSAI P, SISáK I. The role of geology in the spatial prediction of soil properties in the watershed of Lake Balaton, Hungary[J]. Geologia Croatica, 2018, 71(1): 29-39.
[8] SPINOLA D, PORTES R, FEDENKO J, et al. Lithological controls on soil geochemistry and clay mineralogy across Spodosols in the coastal temperate rainforest of southeast Alaska[J]. Geoderma, 2022, 428: 116211.
[9] NOVOSELOV A A, HODSON M E, GATICA J T, et al. The effect of rock lithology on the background concentrations of trace elements in alluvial soils: Implications for environmental regulation[J]. Applied Geochemistry, 2022, 146: 105440.
[10]夏学齐,季峻峰,杨忠芳,等.母岩类型对土壤和沉积物镉背景的控制:以贵州为例[J].地学前缘,2022,29(4):438-447. XIA X Q, JI J F, YANG Z F, et al. Parent rock type control on cadmium background in soil and sediment: An example from Guizhou Province[J]. Earth Science Frontiers, 2022, 29(4): 438-447.
[11]罗贤冬,王伟,安邦,等.安徽省潜山县地质背景、土壤类型对土壤有益微量元素含量的综合影响[J].华东地质,2021,42(2):210-216. LUO X D, WANG W, AN B, etal. Comprehensive influence of geological background and soil type on the content of soil beneficial trace elements in Qianshan County, Anhui Province[J]. East China Geology, 2021, 42(2): 210-216.
[12]王春,陈梓杰,王莹,等.黑色岩系地质高背景区土壤锌富集特征与环境活性[J].地球与环境,2022,50(4):490-497. WANG C, CHEN Z J, WANG Y, et al. Accumulation and environmental availability of zinc in soils from a high geological background area underlain by black shale[J]. Earth and Environment, 2022, 50(4): 490-497.
[13]李樋,刘小念,刘洪,等.基于地质建造的土壤营养元素空间分布特征研究——以大凉山区为例[J].安全与环境工程,2021,28(6):127-137. LI T, LIU X N, LIU H, et al. Study on spatial distribution characteristics of soil nutrient elements based on geological construction [J]. Safety and Environmental Engineering, 2021, 28(6): 127-137.
[14]《地球科学大辞典》编委会. 地球科学大辞典[M]. 北京:地质出版社,2006:863. Editorial Board of the "Dictionary of Earth Sciences". Dictionary of Earth Sciences [M]. Beijing: Geology Press, 2006:863.
[15]徐颖菲,张耿苗,张丽君,等.亚热带不同母岩成壤过程中金属元素的迁移和积累特点[J]. 浙江农业学报,2019,31(12):2064-2072. XU Y F, ZHANG G M, ZHANG L J, et al. Migration and accumulation of metal elements during formation of soils derived from different parent rocks in subtropical zone [J]. Acta Agriculturae Zhejiangensis, 2019, 31(12): 2064-2072.
[16]LEITGEB E, GHOSH S, DOBBS M, et al. Distribution of nutrients and trace elements in forest soils of Singapore [J]. Chemosphere, 2019, 222: 62-70.
[17]陈方舟,王瑞芳.新安江流域生态补偿机制长效化研究[J].人民长江,2021,52(2):44-49. CHEN F Z, WANG R F. Study on long-acting effect of ecological compensation mechanism in Xin’an River Basin[J]. Yangtze River, 2021, 52(2): 44-49.
[18]王美华.浙西典型石煤矿山周边耕地富硒土壤地球化学特征及影响因素[J].现代地质,2022,36(3):941-952. WANG M H. Geochemical characteristics and influencing factors of selenium-enriched soils in cultivated land around typical stone coal mines in Western Zhejiang [J]. Geoscience, 2022, 36(3): 941-952.
[19]张爽,章明奎.浙西石灰岩发育土壤镉的积累及其成土过程中镉的淋失特征[J].浙江大学学报(农业与生命科学版),2020,46(5):591-598. ZHANG S, ZHANG M K. Cadmium accumulation in soils developed from limestone and leaching characteristics of cadmium during development of the soils in western Zhejiang Province[J]. Journal of Zhejiang University (Agric. ＆ Life Sci.), 2020,46(5):591-598.
[20]邢润华,隋新新.安徽省宣城市南部地区土壤重金属元素地球化学特征[J]. 岩石矿物学杂志,2022,41(1):185-194. XING R H, SUI X X. Geochemical characteristics of the heavy metals in soil, the south of Xuancheng, Anhui Province [J]. Acta Petrologica et Mineralogica, 2022, 41(1): 185-194.
[21]潘桂棠,肖庆辉,陆松年,等.中国大地构造单元划分[J].中国地质,2009,36(1):1-28. PANG G T, XIAO Q H, LU S N, et al. Subdivision tectonic units of China [J]. Geology in China, 2009, 36(1): 1-28.
[22]LIU Y Z, XIAO T F, PEKINS R B, et al. Geogenic cadmium pollution and potential health risks, with emphasis on black shale [J]. Journal of Geochemical Exploration, 2017, 176: 42-49.
[23]刘意章,陈梓杰,叶太平,等.重庆巫山地区上二叠统黑色岩系中镉等有害元素赋存状态及环境意义[J].矿物岩石地球化学通报,2021,40(4):938-945. LIU Y Z, CHEN Z J, YE T P, et al. Occurrences of toxic elements in upper Permian black shales at Wushan area and their environmental implication [J]. Bulletin of Mineralogy Petrology and Geochemistry, 2021, 40(4): 938-945.
[24]WEI W, LING S X, WU X Y, et al. Geochemical accumulation and source tracing of heavy metals in arable soils from a black shale catchment, southwestern China [J]. Science of the Total Environment, 2023, 857: 159467.
[25]中国地质调查局.DD2005—03生态地球化学评价样品分析技术要求(试行)[S].北京:中国标准出版社,2005. China Geological Survey. DD2005—03 Technical requirements for analysis of eco-geochemical evaluation samples (Trial) [S].Beijing: Standards Press of China,2005.
[26]唐志敏,白晓,湛龙,等.福建省长汀县重点水土流失区土壤元素地球化学特征及其指示意义[J].华东地质,2022,43(3):324-335. TANG Z M, BAI X, ZHAN L, et al. Geochemical characteristics and its indicative significance of soil elements in key soil erosive areas of Changting County, Fujian Province [J]. East China Geology, 2022, 43(3): 324-335.
[27]鄢明才,顾铁新,迟清华,等.中国土壤化学元素丰度与表生地球化学特征[J].物探与化探,1997,21(3):161-167. YAN M C, GU T X, CHI Q H, etal. Abundance of chemical elements of soils in China and supergenesis geochemistry characteristics [J]. Geophysical and Geochemical Exploration, 1997, 21(3): 161-167.
[28]YAN M C, CHI Q H. The chemical composition of the continental crust and rocks in the eastern part of China [M]. Beijing: Science Press, 2005: 171.
[29]中华人民共和国国土资源部.DZ/T 0295—2016土地质量地球化学评价规范[S].北京:中国标准出版社,2016. Ministry of Land and Resources of the People’s Republic of China. DZ/T 0295—2016 Specification of land quality geochemical assessment[S].Beijing: Standards Press of China,2016.
[30]邢润华,吴正,杜国强.安徽省宣州区土壤重金属污染风险评估及来源分析[J].华东地质,2022,43(4):336-344. XING R H, WU Z, DU G Q. Risk assessment and source analysis of soil heavy metal pollution in Xuanzhou District, Anhui Province[J]. East China Geology, 2022, 43(3): 336-344.
[31]中华人民共和国环境保护部,国家质量监督检验检疫总局.GB 15618—2018土壤环境质量农用地土壤污染风险管控标准(试行)[S].北京:中国环境科学出版社,2018:1-4. Ministry of Environmental Protection of the People’s Republic of China, General Administration of Quality Supervision, Inspection and Quarantine. GB 15618—2018 Soil environmental quality, risk control standard for soil contamination agricultural land(Trial) [S].Beijing: China Environmental Science Press,2018:1-4.
[32]XIA X Q, JI J F, ZHANG C S, et al. Carbonate bedrock control of soil Cd background in Southwestern China: Its extent and influencing factors based on spatial analysis [J]. Chemosphere, 2022, 290: 133390.
[33]YANG Q, YANG Z F, FELIPPELLI G M, et al. Distribution and secondary enrichment of heavy metal elements in karstic soils with high geochemical background in Guangxi, China [J]. Chemical Geology, 2021, 567: 120081.
[34]KULP T R, PRATT L M. Speciation and weathering of selenium in Upper Cretaceous chalk and shale from South Dakota and Wyoming, USA[J]. Geochimica et Cosmochimica Acta, 2004, 68(18): 3687-3701.
[35]NI R X, LUO K L, TIAN X L, et al. Distribution and geological sources of selenium in environmental materials in Taoyuan County, Hunan Province, China[J]. Environmental Geochemistry and Health, 2016, 38(3): 927-938.

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备注/Memo

备注/Memo:
收稿日期:2023-2-9;改回日期:2023-3-25。
基金项目:中国地质调查局"华东地区自然资源动态监测与风险评估(编号:DD20230103)"、国家自然科学基金"武功山地区早古生代不同成分花岗质岩石的成因与地壳熔融机制研究(编号:42002058)"和国家自然科学基金"基于空间先验与贝叶斯决策的高分遥感影像城市地表覆盖变化检测(编号:41901310)"项目联合资助。
作者简介:唐志敏,1992年生,男,工程师,硕士,主要从事生态地球化学研究工作。Email:894431121@qq.com。
更新日期/Last Update: 1900-01-01