[1]陶小虎,王赫生,龚建师,等.苏北阜宁县地下水水化学特征及成因分析[J].华东地质,2023,44(03):357-366.[doi:10.16788/j.hddz.32-1865/P.2023.03.011]
　TAO Xiaohu,WANG Hesheng,GONG Jianshi,et al.Hydrochemical characteristics and genesis of the groundwater in Funing County, Northern Jiangsu[J].East China Geology,2023,44(03):357-366.[doi:10.16788/j.hddz.32-1865/P.2023.03.011]
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苏北阜宁县地下水水化学特征及成因分析()
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《华东地质》[ISSN:2096-1871/CN:32-1865/P]

卷:
44
期数:
2023年03期
页码:
357-366
栏目:
长江经济带资源与环境专辑
出版日期:
2023-09-28

文章信息/Info

Title:
Hydrochemical characteristics and genesis of the groundwater in Funing County, Northern Jiangsu
作者:
陶小虎1; 4;  王赫生1; 4;  龚建师1; 4;  许乃政1; 4;  檀梦皎1; 4;  胡小雨2;  戴飞虎3;  孟显超3;  朱春芳1; 4;  周锴锷1; 4;  李亮1; 4
1. 中国地质调查局南京地质调查中心, 江苏 南京 210016;
2. 江苏省水资源服务中心, 江苏 南京 210029;
3. 阜宁县自然资源和规划局, 江苏 盐城 224400;
4. 自然资源部流域生态地质过程重点实验室, 江苏 南京 210016
Author(s):
TAO Xiaohu1; 4;  WANG Hesheng1; 4;  GONG Jianshi1; 4;  XU Naizheng1; 4;  TAN Mengjiao1; 4;  HU Xiaoyu2;  DAI Feihu3;  MENG Xianchao3;  ZHU Chunfang1; 4;  ZHOU Kaie1; 4;  LI Liang1; 4
1. Nanjing Center, China Geology Survey, Nanjing 210016, Jiangsu, China;
2. Water Resources Service Center of Jiangsu Province, Nanjing 210029, Jiangsu, China;
3. Funing Bureau of Natural Resources and Planning, Yancheng 224400, Jiangsu, China;
4. Key Laboratory of Watershed Eco-Geological Processes, Ministry of Natural Resources, Nanjing 210016, Jiangsu, China
关键词:
阜宁县; 地下水; 水化学特征; 氢氧同位素; 水化学成因
Keywords:
Funing County; groundwater; hydrochemical characteristics; hydrogen and oxygen isotopes; hydrochemical genesis
分类号:
X523
DOI:
10.16788/j.hddz.32-1865/P.2023.03.011
摘要:
为了查明苏北阜宁县潜水和承压水的水化学成因和补给特征,文章采集区域内地表水、潜水、承压水(第Ⅱ、第Ⅲ、第Ⅳ承压水)的水样,结合数理统计分析、Piper三线图、Gibbs模型和水化学特征系数等手段,分析了不同水体的氢氧同位素关系和矿化度分布、主要阴阳离子关系、水化学特征。结果表明:① 阜宁县地下水总体为弱碱性,潜水和承压水中阳离子质量浓度都呈现Na+>Ca2+>Mg2+>K+,潜水中阴离子质量浓度呈现HCO-3>Cl->SO2-4>NO-3,第Ⅱ、第Ⅲ、第Ⅳ承压水中阴离子质量浓度皆呈现出HCO-3>SO2-4>Cl->NO-3;潜水的总溶解固体(TDS)比第Ⅱ、第Ⅲ、第Ⅳ承压水偏高,局部区域的潜水为微咸水和咸水,第Ⅱ、第Ⅲ、第Ⅳ承压水的水质明显优于潜水。② 地下水的补给与大气降水相关,潜水为现代降水补给,第Ⅱ、第Ⅲ、第Ⅳ承压水源于晚更新世或者更早时期的降水补给。③ 地下水水化学特性受降水影响较小,主要受到水岩作用、阳离子交换作用控制,其中第Ⅱ、第Ⅲ、第Ⅳ承压水的盐分主要来源于硅酸盐岩风化,人类活动对地下水化学组分影响相对较弱。
Abstract:
For investigating hydrochemical evolution and recharge characterisitcs of the groundwater in Funing County, northern Jiangsu Province, the study collected various water samples from regional surface water, phreatic water and confined water (the Ⅱ, Ⅲ and Ⅳ confined water) and analyzed their hydrogen and oxygen isotopes (δ18O-δD) relations, distributive rules of water salinity, major ions’ relations and hydrochemical characteristics in combination of mathematical statistical analysis, Piper three-line diagram, Gibbs model and hydrochemical characteristic coefficient. The results show that: ① the groundwater in Funing is weakly alkaline in general, mass concentration of cations in both phreatic water and confined water are distributed in the sequence of Na+>Ca2+>Mg2+>K+; those of anions in the phreatic water presents as HCO-3>Cl->SO2-4>NO-3while that in the Ⅱ, Ⅲ and Ⅳ confined water presents as HCO-3>SO2-4>Cl->NO-3; The total dissolved solids (TDS) of the phreatic water is relatively higher than that of the Ⅱ, Ⅲ and Ⅳ confined water, with locally brackish and saline water; The water quality in the confined area is significantly better than that in the phreatic area. ② The groundwater recharge in the study area is related to the atmospheric precipitation. The phreatic water is closely associated with modern precipitation while the Ⅱ, Ⅲ and Ⅳ confined water mainly sourced from precipitation replenishment in Late Pleistocene or even earlier; ③ The chemical characteristics of groundwater in the region are less affected by precipitation and more controlled by water rock interaction and cation exchange, among which the salinity of the Ⅱ, Ⅲ, and Ⅳ confined water mainly come from the weathering of silicate rocks, and human activities have slight impact on the chemical composition of the groundwater.

参考文献/References:

[1] 陈万里,顾洪群.江苏第四纪海侵及近代海岸变迁研究[J].江苏地质,1998,22(A12):45-50. CHEN W L, GU H Q. Quaternary transgression and modern costal changes in Jiangsu[J]. Jiangsu Geology, 1998, 22(A12):45-50.
[2] 薛春汀,刘健,孔祥淮.全新世淮河三角洲初步研究[J].第四纪研究, 2010, 30(5):892-901. XUE C T, LIU J, KONG X H. Preliminary study of holocene Huaihe river delta on west coastal plain of Yellow Sea, China[J]. Quaternary Sciences, 2010, 30(5):892-901.
[3] 黄敬军,陆华.江苏沿海地区深层地下水开发利用现状及环境地质问题[J].水文地质工程地质,2004, 31(6):64-68. HUANG J J, LU H. Aquifers and environmental geological problems in the coastal areas in Jiangsu Province[J]. Hydrogeology and Engineering Geology, 2004, 31(6):64-68.
[4] 康博.江苏沿海地区地下水演化与合理开发利用研究[D].长春:吉林大学, 2017. KANG B. The study of groundwater evolution and rational exploitation and utilizing in Jiangsu coastal area[D]. Changchun:Jilin University, 2017.
[5] 李亮,龚建师,王赫生,等.安徽省亳州市浅层地下水化学特征及成因机理[J/OL].(2023-02-09).https://9.cglhub.com/detail_38502727e7500f26c36d01340c0bf98c42552f13171bea581921b0a3ea255101fc1cf1fbb4666ae6fe8645b7c867bb740397903f685bfc4e8ef4bd4b89669aa6c9d2a74ed67614001ccc2d2ce9375a4e?. LI L, GONG J S, WANG H S, et al. Hydrochemical characteristics and formation mechanism of shallow groundwater in Bozhou City, Anhui Province[J/OL].(2023-02-09).https://9.cglhub.com/detail_38502727e7500f26c36d01340c0bf98c42552f13171bea581921b0a3ea255101fc1cf1fbb4666ae6fe8645b7c867bb740397903f685bfc4e8ef4bd4b89669aa6c9d2a74ed67614001ccc2d2ce9375a4e?.
[6] 王晓曦,王文科,王周锋,等.滦河下游河水及沿岸地下水水化学特征及其形成作用[J].水文地质工程地质,2014,41(1):25-33,73. WANG X X, WANG W K, WANG Z F, et al. Hydrochemical characteristics and formation mechanism of river water and groundwater along the downstream Luanhe River,northeastern China[J]. Hydrogeology&Engineering Geology, 2014, 41(1):25-33,73.
[7] 金阳,姜月华,周权平,等.丹阳市吕城地区浅层地下水演化特征及成因[J].华东地质,2021,42(4):475-482. JIN Y, JIANG Y H, ZHOU Q P, et al. Evolution charactistics and Genesis of shallow groundwater in Lvcheng area of Danyang city[J]. East China Geology, 2021, 42(4):475-482.
[8] 张春潮,侯新伟,李向全,等.三姑泉域岩溶地下水水化学特征及形成演化机制[J].水文地质工程地质,2021,48(3):62-71. ZHANG C C, HOU X W, LI X Q, et al. Hydrogeochemical characteristics and evolution mechanism of karst groundwater in the catchment area of the Sangu Spring[J]. Hydrogeology&Engineering Geology, 2021, 48(3):62-71.
[9] 李志红,胡伏生,周文生,等.银川地区承压水水化学特征及控制因素[J].水文地质工程地质, 2017, 44(2):31-39. LI Z H, HU F S, ZHOU W S, et al. Hydrogeochemical characteristics and controlling factors of confined water in Yinchuan[J]. Hydrogeology&Engineering Geology, 2017, 44(2):31-39.
[10] WEN Y, QIU J H, CHENG S, et al. Hydrochemical evolution mechanisms of shallow groundwater and its quality assessment in the Estuarine Coastal Zone:a case study of Qidong, China[J]. Int. J. Environ. Res. Public Health, 2020, 17:3382.
[11] 钱会,马致远.水文地球化学[M].北京:地质出版社, 2005. QIAN H, MA Z Y. Hydrogeochemistry[M]. Beijing:The Geological Publishing House, 2005.
[12] 陈建生,韩莉文,马芬艳.苏北平原隐伏玄武岩地下水研究[J].河海大学学报(自然科学版), 2022, 50(6):1-8. CHEN J S, HAN L W, MA F Y. Study on the concealed basalt groundwater in Subei Plain[J]. Journal of Hohai University (Natural Sciences), 2022, 50(6):1-8.
[13] 卞锦宇,方瑞.盐城市地下水水质控制因素分析[J].水文地质工程地质,2003,30(5):56-60. BIAN J Y, FANG R. Analysis of controlling factors of groundwater quality in Yancheng area[J]. Hydrogeology&Engineering Geology, 2003,30(5):56-60.
[14] 张岩,付昌昌,毛磊,等.江苏盐城地区地下水水化学特征及形成机理[J].长江流域资源与环境,2017,26(4):598-605. ZHANG Y, FU C C, MAO L, et al. Hydrochemical characteristics and formation mechanism of the groundwater in Yancheng, Jiangsu province[J]. Resources and Environment in the Yangtze Basin, 2017, 26(4):598-605.
[15] 王建,张华兵,许君利,等.盐城地区地下水溶质来源及其成因分析[J].环境科学,2022,43(4):1908-1919. WANG J, ZHANG H B, XU J L, et al. Provenance of groundwater solute and its controlling factors in Yancheng area[J]. Environmental Science, 2022,43(4):1908-1919.
[16] 王建,茅悦,许君利,等.江苏盐城地区地下水质量评估与成因分析[J].安徽农业大学学报,2023,50(1):116-125. WANG J, MAO Y, XU J L, et al. Groundwater quality and cause analysis in Yancheng area, Jiangsu Province[J]. Journal of Anhui Agricultural University, 2023, 50(1):116-125.
[17] 刘彦,龚绪龙,李进,等.苏北海岸带浅部弱透水层孔隙水咸化过程[J].水资源与水工程学报, 2021, 32(1):57-62,71. LIU Y, GONG X L, LI J, et al. Salinization process of shallow aquitard porewater in north Jiangsu coastal zone[J]. Journal of Water Resources&Water Engineering, 2021, 32(1):57-62,71.
[18] 侯国华,高茂生,党显璋,等.江苏盐城滨海地区浅层地下咸水的水盐来源及咸化成因[J].海洋地质与第四纪地质,2020,41(4):48-59. HOU G H, GAO M S, DANG X Z, et al. Water and salt sources and salinization of shallow saline groundwater in the coastal area of Yancheng, Jiangsu[J]. Marine Geology&Quaternary Geology, 2020, 41(4):48-59.
[19] 中华人民共和国自然资源部.DZ0064-2021地下水质分析方法[S]. Ministry of Natural Resources of the People’s Republic of China. DZ 0064-2021 Methods for analysis of groundwater quality[S].
[20] 周慧芳,谭红兵,张西营,等.江苏南通地下水补给源、水化学特征及形成机理[J].地球化学,2011,40(6):566-576. ZHOU H F, TAN H B, ZHANG X Y, et al. Recharge source, hydrochemical characteristics and formation mechanism of groundwater in Nantong, Jiangsu Province[J]. Geochimica, 2011, 40(6):566-576.
[21] 苟富刚,龚绪龙,李进,等.江苏滨海平原微承压水层位水土体含盐特征及其相关性分析[J].水资源与水工程学报,2017,28(3):72-76. GOU F G, GONG X L, LI J, et al. Salt characteristics and correlation analysis of soil and water body of micro confined water layer in Jiangsu coastal plain[J]. Journal of Water Resources&Water Engineering, 2017, 28(3):72-76.
[22] 刘春雷,李亚松,曹胜伟,等.福建省厦门市水热型地热系统地球化学特征及成因模式.华东地质,2023,44(2):128-140. LIU C L,LI Y S,CAO S W,et al.Geochemical characteristics and genetic model of hydro-geothermal system in Xiamen City, Fujian Province.East China Geology, 2023,44(2):128-140.
[23] CRAIG H. Isotopic variations in meteoric waters[J]. Science, 1961, 133:1702-1703.
[24] 杨楠,苏春利,曾邯斌,等.基于水化学和氢氧同位素的兴隆县地下水演化过程研究[J].水文地质工程地质, 2020, 47(6):154-162. YANG N, SU C L, ZENG H B, et al. Evolutional processes of groundwater in Xinglong County based on hydrochemistry and hydrogen and oxygen isotopes[J]. Hydrogeology&Engineering Geology, 2020, 47(6):154-162.
[25] 汪少勇,何晓波,丁永建,等.长江源多年冻土区地下水氢氧稳定同位素特征及其影响因素[J].环境科学,2020,41(1):166-172. WANG S Y, HE X B, DING Y J, et al. Characteristics and influencing factors of stable hydrogen and oxygen isotopes in groundwater in the permafrost region of the source region of the Yangtze River[J]. Environmental Science, 2020, 41(1):166-172.
[26] GIBBS R J. Mechanisms controlling world water chemistry[J]. Science, 1970, 170(3962):1088-1090.
[27] 国家市场监督管理总局,国家标准化管理委员会.GB5749-2022生活饮用水卫生标准.北京:中国标准出版社, 2022:1-10. State Administration for Maket Regulation, Standardization Administration. GB5749-2022 Standards for drinking water quality. Beijing:Standards Press of China, 2022:1-10.
[28] FAN B L, ZHAO Z Q, TAO F X, et al.Characteristics of carbonate, evaporite and silicate weathering in Huanghe River basin:a comparison among the upstream, midstream and downstream[J]. Journal of Asian Earth Sciences, 2014, 96:17-26.
[29] ROY S, GAILLARDET J, ALLEGRE C J. Geochemistry of dissolved and suspended loads of the Seine river, France:anthropogenic impact, carbonate and silicate weathering[J]. Geochimica et Cosmochimica Acta,1999,63(9):1277-1292.
[30] 郑涛,焦团理,胡波,等.涡河流域中部地区地下水化学特征及其成因分析[J].环境科学,2021,42(2):766-775. ZHENG T, JIAO T L, HU B, et al. Hydrochemical characteristics and origin of groundwater in the central Guohe River basin[J]. Environmental Science, 2021, 42(2):766-775.

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备注/Memo

备注/Memo:
收稿日期:2023-3-15;改回日期:2023-6-13。
基金项目:中国地质调查局"长江下游及淮河流域水文地质与水资源调查监测(编号:DD20221756)"、"淮河南系水文地质与水资源调查监测(编号:DD20230428)"项目联合资助。
作者简介:陶小虎,1987年生,男,工程师,博士,主要从事地下水环境研究。Email:taoxiaohu_cgs@126.com。
通讯作者:王赫生,1984年生,男,高级工程师,博士研究生,主要从事水工环地质调查研究。Email:411099641@qq.com。
更新日期/Last Update: 1900-01-01